1.Preheat oven to 170°C. Grease a deep 22cm bundt pan well.
2.Beat butter, sugar, extract and peanut butter in a large bowl with an electric mixer until light and fluffy. Beat in eggs, one at a time. Sift flours and soda over butter mixture; stir to combine. Stir in buttermilk. Spread mixture into pan; smooth surface.
3.Bake cake about 1 hour. Stand in pan 5 minutes; turn onto a wire rack to cool completely.
4.Meanwhile, make chocolate glaze. Stir chopped chocolate and thickened cream into a small saucepan over low heat until smooth. Stand about 30 minutes or until thick.
5.Pour glaze over cooled cake; stand 15 minutes before serving.
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